Mark 1:35
35 Very early in the morning, while it was still dark, Jesus got up, left the house and went off to a solitary place, where he prayed.
If you are a morning person, this is by far the best time to spend alone with God. Now remember, Jesus is divine and so he appears to be a night person and a morning person! You just need to pick one as the best time for you to be alone with him.
Pray for the desire to spend more alone time with Jesus.